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Bimodal coordination of fused arenes to a Pd 3 cluster site.
Chemical Communications : Chem Comm 2018 June 6
We report bimodal coordination behaviour of fused arenes at a Pd3 cluster site. A cyclooctatetraene-supported Pd3 cluster accommodates anthracene and tetracene in an oxidative π-addition manner, whereas triphenylene and fluoranthene are accommodated in a π-coordination manner.
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