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A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties.

We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2- polyanionic zigzag chains, which shows above-room-temperature switching of quadratic nonlinear optical (NLO) properties induced by the unique order-disorder conformational changes of the organic cation.

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