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Polyoxometalate-Based Metal-Organic Frameworks as Visible-Light-Induced Photocatalysts.
Inorganic Chemistry 2018 May 8
Two stable 3D polyoxometalate-based metal-organic frameworks (PMOFs), [CuI 12 (trz)8 (H2 O)2 ][α-SiW12 O40 ]·2H2 O (1) and [CuI 12 (trz)8 Cl][α-PW12 O40 ] (2) (Htrz = 1- H-1,2,4-triazole) based on Keggin-type POMs were successfully obtained and fully characterized. The basic building units of the two PMOFs are [CuI 12 (trz)8 ], but polyoxoanion (POA) template effect leads to different structures and properties: 1 represents an interesting example that [α-SiW12 O40 ]4- locate in the nine-membered Cu-trz rings through Cu···O weak interactions to form a 3D framework, whereas 2 shows a 3D structure constructed from 2D bilayer cationic network [CuI 12 (trz)8 Cl]3+ and [α-PW12 O40 ]3- lying in the adjacent layers via Cu···O weak interactions. PMOF 1 as unusual visible-light photocatalyst exhibit significantly enhanced photocatalytic activity under visible-light and excellent stability during the photocatalysis process for recovering and recycling, as well as photocatalytic hydrogen evolution activity.
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