A kinetic study on the catalysis of KCl, K 2 SO 4 , and K 2 CO 3 during oxy-biomass combustion.

Biomass combustion under the oxy-fuel conditions (Oxy-biomass combustion) is one of the approaches achieving negative CO2 emissions. KCl, K2 CO3 and K2 SO4 , as the major potassium species in biomass ash, can catalytically affect biomass combustion. In this paper, the catalysis of the representative potassium salts on oxy-biomass combustion was studied using a thermogravimetric analyzer (TGA). Effects of potassium salt types (KCl, K2 CO3 and K2 SO4 ), loading concentrations (0, 1, 3, 5, 8 wt%), replacing N2 by CO2 , and O2 concentrations (5, 20, 30 vol%) on the catalysis degree were discussed. The comparison between TG-DTG curves of biomass combustion before and after water washing in both the 20%O2 /80%N2 and 20%O2 /80%CO2 atmospheres indicates that the water-soluble minerals in biomass play a role in promoting the devolatilization and accelerating the char-oxidation; and the replacement of N2 by CO2 inhibits the devolatilization and char-oxidation processes during oxy-biomass combustion. In the devolatilization stage, the catalysis degree of potassium monotonously increases with the increase of potassium salt loaded concentration. The catalysis degree order of the studied potassium salts is K2 CO3  > KCl > K2 SO4 . In the char-oxidation stage, with the increase of loading concentration the three kinds of potassium salts present inconsistent change tendencies of the catalysis degree. In the studied loading concentrations from 0 to 8 wt%, there is an optimal loading concentration for KCl and K2 CO3 , at 3 and 5 wt%, respectively; while for K2 SO4 , the catalysis degree on char-oxidation monotonically increases with the loading potassium concentration. For most studied conditions, regardless of the potassium salt types or the loading concentrations or the combustion stages, the catalysis degree in the O2 /CO2 atmosphere is stronger than that in the O2 /N2 atmosphere. The catalysis degree is also affected by the O2 concentrations, and the lowest catalysis degree is generally around 20 vol% O2 concentration. The kinetic parameters under the different studied conditions are finally obtained.