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Oxidation-induced generation of a mild electrophile for proximity-enhanced protein-protein crosslinking.
Chemical Communications : Chem Comm 2018 April 20
We report a strategy to introduce a reactive electrophile into proteins through the conversion of a chemically inert group into a bioreactive group in response to an inducer molecule. This strategy was demonstrated by oxidation-induced and proximity-enhanced protein-protein crosslinking in the presence of a large excess of free nucleophile.
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