Add like
Add dislike
Add to saved papers

Determination of mercury (II) ions based on silver-nanoparticles-assisted growth of gold nanostructures: UV-Vis and surface enhanced Raman scattering approaches.

Innovative dual detection methods for mercury(II) ions (Hg(II) ) have been developed based on the formation of gold nanostructures (AuNSs) following the addition of mercury-containing solution to a mixture containing an optimized amount of Au(III) , H2 O2 , HCl, and silver nanoparticles (AgNPs). In the absence of Hg(II) , the addition of Au(III) , H2 O2 , and HCl to the AgNP solution changes the solution's color from yellow to red, and the absorption peak shifts from 400 to 526nm, indicating the dissolution of AgNPs and the formation of gold nanoparticles (AuNPs). Because of the spontaneous redox reaction of Hg(II) toward AgNPs, the change in the amount of remaining AgNP seed facilitates the generation of irregular AuNSs, resulting in changes in absorption intensity and shifting the peak within the range from 526 to 562nm depending on the concentration of Hg(II) . Under optimal conditions, the limit of detection (LOD) for Hg(II) at a signal-to-noise ratio (S/N) of 3 was 0.3μM. We further observed that AgNP-assisted catalytic formation of Au nanomaterials deposited on a surface enhanced Raman scattering active substrate significantly reduced the Raman signal of 4-mercaptobenzoic acid, dependent on the Hg(II) concentration. A linear relationship was observed in the range 0.1nM-100μM with a LOD of 0.05nM (S/N 3.0). As a simple, accurate and precise method, this SERS-based assay has demonstrated its success in determining levels of Hg(II) in real water samples.

Full text links

We have located links that may give you full text access.
Can't access the paper?
Try logging in through your university/institutional subscription. For a smoother one-click institutional access experience, please use our mobile app.

For the best experience, use the Read mobile app

Mobile app image

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app

All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.

By using this service, you agree to our terms of use and privacy policy.

Your Privacy Choices Toggle icon

You can now claim free CME credits for this literature searchClaim now

Get seemless 1-tap access through your institution/university

For the best experience, use the Read mobile app