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Supramolecular assemblies of dinuclear alkynylplatinum(ii) terpyridine complexes with double-decker silsesquioxane nano-cores: the role of isomerism in constructing nano-structures.

Isomeric double-decker silsesquioxane-functionalized dinuclear alkynylplatinum(ii) terpyridine complexes demonstrate self-association behaviours via the stabilisation of hydrophobic, PtPt and/or π-π stacking interactions. These supramolecular architectures and molecular packings are found to be closely related to the isomeric configurations of the complexes and have been investigated using various spectroscopic studies.

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