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Insect growth regulatory activity of carvacrol-based 1,3,4-thiadiazoles and 1,3,4-oxadiazoles.
Molecular Diversity 2018 August
In designing of novel insect growth regulators (IGRs), biologically occurring carvacrol has been structurally modified to thiadiazole and oxadiazole moieties. Two series of carvacrol analogs containing 1,3,4-thiadiazole (VIIIa-e) and 1,3,4-oxadiazole (IXa-e) derivatives are designed and synthesized. Their structures are confirmed by FT-IR, [Formula: see text] NMR, [Formula: see text]C NMR and LC-MS. IGR activity is tested against Spodoptera litura. Several analogs displayed IGR activity against this insect pest. Compounds VIIIe and IXe displayed relatively good IGR activity with [Formula: see text]values 117.43 and 108.83 ppm against Spodoptera litura, respectively. Synthesis, characterization and evaluation of carvacrol-based 1,3,4-thiadiazole and 1,3,4-oxadiazole derivatives as potent insect growth regulators (IGRs).
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