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Covalent functionalization of black phosphorus nanoflakes by carbon free radicals for durable air and water stability.

Haiguo Hu, Hong Gao, Lili Gao, Feng Li, Na Xu, Xuefeng Long, Yiping Hu, Jun Jin, Jiantai Ma
Nanoscale 2018 March 30
This work developed a simple and efficient method to covalently functionalize black phosphorus nanoflakes (BPNFs) with carbon free radicals from azodiisobutyronitrile (AIBN) molecules. BPNFs after successful modification (BPNFs-AIBN) not only had good stability in air and aqueous solution, but also still maintained good optical properties.

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