We have located links that may give you full text access.
Lower ammoniation activation energy of CoN nanosheets by Mn doping with superior energy storage performance for secondary ion batteries.
Nanoscale 2018 March 29
Cationic doping has been regarded as an effective strategy to improve the electrochemical performance of transition metal composites for lithium ion batteries (LIBs). Herein, we report manganese doped cobalt nitrides (Mn0.33 Co0.67 N) as a novel anode material for LIBs with a high reversible capacity close to 900 mA h g-1 after 150 cycles at a current density of 0.5 A g-1 , which is superior to 749 mA h g-1 of undoped CoN. The most fascinating performance of Mn0.33 Co0.67 N is the rate capability, in which 91% of capacity is maintained when the current density increases ten-fold from 0.2 A g-1 to 2.0 A g-1 . This enhanced electrochemical performance is attributed to the fact that Mn doping makes it faster to regenerate Co-N bonds, as evidenced by a calculated apparent ammoniation activation energy (Ea ) decrease from 113 kJ mol-1 to 96 kJ mol-1 . This fast regeneration of Co-N bonds upon conversion reactions is believed to prevent the nitride electrode from a partial loss of charge capacity upon high rate cycling, in turn facilitating the extrinsic pseudocapacitive contribution.
Full text links
Related Resources
Trending Papers
Challenges in Septic Shock: From New Hemodynamics to Blood Purification Therapies.Journal of Personalized Medicine 2024 Februrary 4
Molecular Targets of Novel Therapeutics for Diabetic Kidney Disease: A New Era of Nephroprotection.International Journal of Molecular Sciences 2024 April 4
The 'Ten Commandments' for the 2023 European Society of Cardiology guidelines for the management of endocarditis.European Heart Journal 2024 April 18
A Guide to the Use of Vasopressors and Inotropes for Patients in Shock.Journal of Intensive Care Medicine 2024 April 14
Diagnosis and Management of Cardiac Sarcoidosis: A Scientific Statement From the American Heart Association.Circulation 2024 April 19
Essential thrombocythaemia: A contemporary approach with new drugs on the horizon.British Journal of Haematology 2024 April 9
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app