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Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex.
Inorganic Chemistry 2018 March 20
Herein a homoleptic rhenium(I) complex bearing three chelating diisocyanide ligands and its photophysical properties are communicated. The complex emits weakly from a high-energy triplet metal-to-ligand charge-transfer excited state with an 8 ns lifetime in deaerated CH3 CN at 22 °C and is shown to act as an efficient photoredox catalyst comparable to [Ir(ppy)3 ] (ppy = 2-phenylpyridine) in representative test reactions.
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