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Giant exchange coupling and field-induced slow relaxation of magnetization in Gd 2 @C 79 N with a single-electron Gd-Gd bond.
Chemical Communications : Chem Comm 2018 March 16
Magnetic properties of the azafullerene Gd2 @C79 N are studied by SQUID magnetometry. The effective exchange coupling constant jGd,e between the Gd spins and the spin of unpaired electron residing on the single-electron Gd-Gd bond is determined to be 170 ± 10 cm-1 . Low temperature AC measurements revealed field-induced millisecond-long relaxation of magnetization.
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