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Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Copper(II)-Mediated [ 11 C]Cyanation of Arylboronic Acids and Arylstannanes.
Organic Letters 2018 March 17
A copper-mediated method for the transformation of diverse arylboron compounds and arylstannanes to aryl-[11 C]-nitriles is reported. This method is operationally simple, uses commercially available reagents, and is compatible with a wide variety of substituted aryl- and heteroaryl substrates. This method is applied to the automated synthesis of high specific activity [11 C]perampanel in 10% nondecay-corrected radiochemical yield (RCY).
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