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Nucleophilic trifluoromethylthiolation of bromoalkynones with AgSCF 3 : C(sp)-SCF 3 bond formation towards ynonyl trifluoromethyl sulfides.
Organic & Biomolecular Chemistry 2018 March 8
An AgSCF3 mediated nucleophilic trifluoromethylthiolation reaction for C(sp)-SCF3 bond formation is reported. This nucleophilic trifluoromethylthiolation reaction of bromoalkynones afforded various useful ynonyl trifluoromethyl sulfides in high yields. Interestingly, the over-addition of AgSCF3 is avoided in our approach.
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