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O-Difluorodeuteromethylation of phenols using difluorocarbene precursors and deuterium oxide.
Organic & Biomolecular Chemistry 2018 March 15
The first O-difluorodeuteromethylation of phenols using commercial diethyl bromodifluoromethylphosphonate and deuterium oxide to prepare various difluorodeuteromethyl aryl ethers is reported. This facile method affords a convenient way to introduce OCF2 D groups into organic molecules.
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