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Expedient cobalt(ii)-catalyzed site-selective C7-arylation of indolines with arylboronic acids.

Pinaki Bhusan De, Sourav Pradhan, Sonbidya Banerjee, Tharmalingam Punniyamurthy
Chemical Communications : Chem Comm 2018 March 7
Cobalt(ii)-catalyzed pyrimidyl directing group-assisted C7 arylation of indolines with arylboronic acids has been developed using Mn(OAc)2 ·4H2 O as an oxidant. The use of cobalt(ii)-PCy3 as a catalyst and broad substrate scope are the important practical features.

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