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Helicenophyrins: Expanded Carbaporphyrins Incorporating Aza[5]helicene and Heptacyclic S-Shaped Aza[5]helicene Motifs.

Bartosz Szyszko, Monika Przewoźnik, Michał J Białek, Agata Białońska, Piotr J Chmielewski, Jakub Cichos, Lechosław Latos-Grażyński
Angewandte Chemie 2018 April 4
Incorporation of phenanthrene into a hexaphyrin(1.1.1.1.1.0) frame resulted in intramolecular ring fusion, thus giving rise to chiral helicenophyrins. These molecules contain helicene and porphyrin features by incorporating either an aza[5]helicene or heptacyclic S-shaped aza[5]helicene.

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