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Aromatically functionalized pseudo-crown ethers with unusual solvent response and enhanced binding properties.
Organic & Biomolecular Chemistry 2018 March 8
Conformational flexibility in the host's structure is often considered detrimental to its binding. Flexible pseudo-crown ethers with aromatic donor/acceptor groups at the chain ends, however, displayed enhanced binding affinity and selectivity, particularly when the direct binding interactions were compromised by unfavorable solvents.
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