The Nature of the Heavy Alkaline Earth Metal-Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster.

The molecular strontium hydride [(Me3 TACD)3 Sr3 (μ3 -H)2 ][SiPh3 ] (2) was isolated as the dark red benzene solvate 2·C6 H6 in 69% yield from the reaction of [Sr(SiPh3 )2 (thf)3 ] (1') with (Me3 TACD)H (1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane). This reaction can be considered as a redox process, with the Brønsted acidic amine proton in (Me3 TACD)H transformed into the hydride by the anion [SiPh3 ]- . Trace amounts of water resulted in the formation of [(Me3 TACD)3 Sr3 (μ3 -H)(μ3 -OH)][SiPh3 ] (2*), which cocrystallized with 2. Single-crystal X-ray diffraction of 2 revealed a substitutional disorder of a bridging hydride with a hydroxide ligand. Hydride complex 2 was also obtained by hydrogenolysis of [(Me3 TACD)Sr(SiPh3 )] (3), although pure 3 proved difficult to isolate. In the presence of a 2-fold excess of (Me3 TACD)H, the reaction with disilyl 1' gave [(Me3 TACD)SiPh3 ] (4). Complex 2 underwent facile H/D exchange with D2 (1 bar), with the anion [SiPh3 ]- decomposing concurrently. In the reaction of 2 with 1,1-diphenylethylene (DPE), the anion [SiPh3 ]- was added to the C═C bond in DPE to give [(Me3 TACD)3 Sr3 H2 ][Ph2 CCH2 SiPh3 ] (5), whereas the cationic cluster [(Me3 TACD)3 Sr3 H2 ]+ remained unchanged. 9-Fluorenone underwent one-electron reduction with 2 to give the paramagnetic ketyl complex [{(Me3 TACD)H}Sr(OC13 H8 • )2 (thf)2 ] (6). These strontium compounds are structurally similar to the lighter calcium congeners, but more reactive, in particular with regard to fast H/D exchange and [SiPh3 ]- anion decomposition. DFT studies on the cationic hydride clusters suggest a more pronounced covalent character for strontium compared to calcium. Disilyl 1, strontium diketyl 6, and the calcium congener of 6, [{(Me3 TACD)H}Ca(OC13 H8 ·)2 ] (10), were also characterized by X-ray diffraction.