The Enhanced Red Emission and Improved Thermal Stability of CaAlSiN₃:Eu 2+ Phosphors by Using Nano-EuB₆ as Raw Material.

Synthesizing phosphors with high performance is still a necessary work for phosphor-converted white light-emitting diodes (W-LEDs). In this paper, three series of CaAlSiN₃:Eu2+ (denoted as CASN:Eu2+ ) phosphors using Eu₂O₃, EuN and EuB₆ as raw materials respectively are fabricated by under the alloy precursor normal pressure nitridation synthesis condition. We demonstrate that CASN:Eu2+ using nano-EuB₆ as raw material shows higher emission intensity than others, which is ascribed to the increment of Eu2+ ionic content entering into the crystal lattice. An improved thermal stability can also be obtained by using nano-EuB₆ due to the structurally stable status, which is assigned to the partial substitution of Eu-O (Eu-N) bonds by more covalent Eu-B ones that leads to a higher structural rigidity. In addition, the W-LEDs lamp was fabricated to explore its possible application in W-LEDs based on blue LEDs. Our results indicate that using EuB₆ as raw materials can provide an effective way of enhancing the red emission and improving the thermal stability of the CASN:Eu2+ red phosphor.