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A mononuclear manganese(iii)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions.
Chemical Communications : Chem Comm 2018 January 32
We report the synthesis of manganese(iii)-peroxo (MnIII (O2 )) and manganese(iii)-hydroperoxo (MnIII (O2 H)) complexes by activating dioxygen (O2 ) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.
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