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Novel ruthenium and iridium complexes of N-substituted carbazole as triplet photosensitisers.
Chemical Communications : Chem Comm 2018 January 26
Novel mono- and di-nuclear Ru(ii) and Ir(iii) complexes, bearing a modified carbazole moiety are synthesised. In comparison to their mononuclear analogues, the homonuclear diatomic complexes (RuCRu and IrCIr), in which the carbazole containing-ligand functions as a bridge, display increased absorbance in the visible region, and give rise to higher singlet oxygen quantum yields.
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