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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Skeletal Reorganization: Synthesis of Diptoindonesin G from Pauciflorol F.
Journal of Organic Chemistry 2018 Februrary 3
Described herein is a novel synthetic approach to diptoindonesin G, a highly potent anticancer oligostilbenoid natural product, from pauciflorol F pentamethyl ether through a skeletal reorganization strategy where oxidative cleavage of the indanone ring system of pauciflorol F and sequential cyclization of the key intermediate allowed direct access to the target skeleton.
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