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Research Support, Non-U.S. Gov't
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Evidence for Aggregation-Induced Emission from Free Rotation Restriction of Double Bond at Excited State.

Jia-Bin Xiong, Ying-Xue Yuan, Lian Wang, Jian-Ping Sun, Wei-Guo Qiao, Hong-Chao Zhang, Miao Duan, Hongwei Han, Song Zhang, Yan-Song Zheng
Organic Letters 2018 January 20
This paper reports that cis-TPE dicycles emit strong fluorescence, while the gem dicycles show almost no emission in solution, demonstrating that the free rotation restriction of the double bond at the excited state is the key factor for AIE effects.

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