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Photochemical Activation of Enediyne Warheads: A Potential Tool for Targeted Antitumor Therapy.
Molecular Pharmaceutics 2018 March 6
Spatial and temporal control over DNA cleavage by photoactivated enediynes can be complemented by additional factors such as the release of internal strain, chelation, pH changes, intramolecular H-bonds, and substituent effects. This review presents design and reactivity of photoactivated enediynes/enynes and analyses the chemical, biological, and photophysical challenges in their applications.
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