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Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand.
Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic ZnII /PdII , PbII /PdII and CuII /PdII complexes in high yielding stepwise or one pot reactions. The catalytic activity of these complexes in Heck coupling and Miyaura borylation reactions was investigated.
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