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Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks.

The crystal structure of the deprotonated monocarba-closo-dodecaborate [12-CN-CB11 H11 ]- is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C-[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

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