We have located links that may give you full text access.
Structure Transformation and Cerium-Substituted Optical Response across the Carbonitridosilicate Solid Solution (La δ Y 1-δ ) 2 Si 4 N 6 C (δ = 0-0.5).
Inorganic Chemistry 2018 January 3
Following an investigation proving La2 Si4 N6 C crystallizes in a monoclinic space group, isostructural to Y2 Si4 N6 C, the reportedly hexagonal (La0.5 Y0.5 )2 Si4 N6 C was reinvestigated to examine the apparent crystal structure change across the solid solution. Initially, calculating the electronic structure and phonon density of states of (La0.5 Y0.5 )2 Si4 N6 C in the P63 mc space group revealed an imaginary phonon mode, which is indicative of a structural instability. Displacing the atoms along the pathway of the imaginary vibration led to a previously unreported space group for carbonitridosilicates, trigonal P31c. The assignment of the trigonal space group was subsequently confirmed by synthesizing (La0.5 Y0.5 )2 Si4 N6 C using high-temperature, solid state synthesis and analyzing the crystal structure with high-resolution synchrotron X-ray powder diffraction. Preparing the solid solution, (Laδ Y1-δ )1.98 Ce0.02 Si4 N6 C (δ = 0-0.5), showed that the crystal structure changes from the monoclinic to the trigonal space group at δ ≈ 0.25. Finally, substituting Ce3+ in the crystal structure to investigate the optical response via steady-state luminescent and photoluminescent quantum yield measurements reveals severe luminescent quenching with increasing La3+ content, due to a combination of absorption of luminescence by the host structure and thermal quenching. These results display the virtue of combining computational and experimental techniques to solve inorganic crystal structures and assess potential phosphor hosts.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app