We have located links that may give you full text access.
Self-assembly of heteroleptic dinuclear silver(i) complexes bridged by bis(diphenylphosphino)ethyne.
We present a study of the self-assembling behaviour in solution of Ag[PF6 ] with one equivalent of an N^N ligand (N^N = 6,6'-dimethyl-2,2'-bipyridine (6,6'-Me2 bpy) or 2,2':6',2''-terpyridine (tpy)), together with either 0.5 or one equivalent of the bridging ligand bis(diphenylphosphino)ethyne (dppa). Each product contains a dinuclear cation, with one or two dppa ligands bridging the two Ag+ centres; 6,6'-Me2 bpy and tpy, respectively, act as chelating ligands. The compounds have been analysed in solution using NMR spectroscopic methods (1 H,1 H{31 P}, COSY, NOESY,13 C, HMQC and HMBC), including room and low temperature measurements.31 P{1 H} NMR spectra recorded at different temperatures allow a deeper insight into the dynamic equilibrium processes. In addition, solution31 P-109 Ag HSQC spectroscopic measurements were performed and show, inter alia, the ratio of the splitting in the F1 dimension and the1 J 31 P-109 Ag coupling constant in the fully coupled HSQC. Single crystal X-ray diffraction yielded two pseudo-polymorphic structures for the doubly-bridged [Ag2 (dppa)2 (tpy)2 ][PF6 ]2 and one for the singly-bridged [Ag2 (dppa)(6,6'-Me2 bpy)2 ][PF6 ]2 .
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app