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Diastereoselective Mannich reactions of pseudo- C 2 -symmetric glutarimide with activated imines.

Tatsuya Ishikawa, Tomoko Kawasaki-Takasuka, Toshio Kubota, Takashi Yamazaki
Beilstein Journal of Organic Chemistry 2017
As an extension of the boron enolate-based aldol reactions, the oxazolidinone-installed bisimide 1a from 3-(trifluoromethyl)glutaric acid was employed for Mannich reactions with tosylated imines 2 as electrophiles to successfully obtain the corresponding adducts in a stereoselective manner.

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