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A Step Closer to Metal-Free Dinitrogen Activation: A New Chapter in the Chemistry of Frustrated Lewis Pairs.

Angewandte Chemie 2018 January 23
The end of the metal age: Recent developments in small-molecule activation and chemical transformations of main-group species pose the question as to whether metal catalysts could be avoided altogether in the activation of dinitrogen. A ground-breaking study by Stephan and co-workers clearly implies that the metal-free activation of N2 with frustrated Lewis pairs may be achievable in the not-too-distant future.

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