We have located links that may give you full text access.
Bond Dissociation Energies of Tungsten Molecules: WC, WSi, WS, WSe, and WCl.
Journal of Physical Chemistry. A 2017 December 15
Resonant two-photon ionization spectroscopy was used to locate predissociation thresholds in WC, WSi, WS, WSe, and WCl, allowing bond dissociation energies to be measured for these species. Because of the high degree of vibronic congestion in the observed spectra, it is thought that the molecules dissociate as soon as the lowest separated atom limit is exceeded. From the observed predissociation thresholds, dissociation energies are assigned as D0 (WC) = 5.289(8) eV, D0 (WSi) = 3.103(10) eV, D0 (WS) = 4.935(3) eV, D0 (WSe) = 4.333(6) eV, and D0 (WCl) = 3.818(6) eV. These results are combined with other data to obtain the ionization energy IE(WC) = 8.39(9) eV and the anionic bond dissociation energies of D0 (W-C- ) = 6.181(17) eV, D0 (W- -C) = 7.363(19) eV, D0 (W-Si- ) ≤ 3.44(4) eV, and D0 (W- -Si) ≤ 4.01(4) eV. Combination of the D0 (WX) values with atomic enthalpies of formation also provides Δf H0K ° values for the gaseous WX molecules. Computational results are also provided, which shed some light on the electronic structure of these molecules.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app