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Cobalt Pincer Complexes for Catalytic Reduction of Carboxylic Acid Esters.

Kathrin Junge, Bianca Wendt, Andrea Cingolani, Anke Spannenberg, Zhihong Wei, Haijun Jiao, Matthias Beller
Chemistry : a European Journal 2018 January 25
A selection of cobalt(I) and cobalt(II) pincer type complexes with different substitution patterns was tested in the catalytic reduction of carboxylic acid esters to alcohols. The cobalt pincer type complex 4 is suitable for the hydrogenation of aromatic as well as aliphatic and cyclic esters. Mechanistic investigation indicated a metal ligand cooperated reaction pathway.

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