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Experimental and Theoretical Approach to Variable Chlorination-Promoted Skeletal Transformations in Fullerenes: The Case of C 102 .
Inorganic Chemistry 2018 April 17
The first example of three alternative chlorination-promoted skeletal transformation pathways in the same fullerene cage is presented. Isolated-pentagon-rule (IPR) C102 (19) undergoes both Stone-Wales rotations to give non-IPR #283794 C102 Cl20 and C2 losses to form nonclassical C98 and non-IPR C96 . X-ray structural characterization of the transformation products and a theoretical study of their formation pathways are reported.
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