Deep eutectic solvent based advance microextraction method for determination of aluminum in water and food samples: Multivariate study.

Preconcentration of aluminum Al3+ was carried out by a novel deep eutectic solvent based ultrasound-assisted liquid phase microextraction (DES-UALPME) method. The deep eutectic solvents (DESs), a green solvent was first time used for enrichment and quantification of very low concentration of Al3+ in water and food samples, prior to analysed by electrothermal atomic absorption spectrometry (ETAAS). In present method it was observed that % recovery of Al-8-hydroxyquinoline chelates efficiently extracted by DES solvent. Pre-enrichment factor and limit of detection were observed to be 50, and 0.032μgL-1 , respectively. Developed procedure was validated with the CRM (SLRS-5 river water) of Al and a good agreement was observed in results of measured value to the certified value. The RSD was calculated as 3.3%. The presented procedure was successfully carried out to different water and food samples.