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Journal Article
Research Support, Non-U.S. Gov't
Copper-Catalyzed Enantioselective Synthesis of β-Boron β-Amino Esters.
Organic Letters 2017 December 2
In this report, the enantioselective, copper-catalyzed borylation of β-amidoacrylates is disclosed. A broad variety of biologically important α-aminoboronates has been prepared with consistently high levels of enantiocontrol using an inexpensive copper catalyst and a commercially available chiral ligand. The method can be applied to the synthesis of novel boron-containing dipeptides and hemiboronates.
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