Structural Insights from 59 Co Solid-State NMR Experiments on Organocobalt(I) Catalysts.

A series of fumarate-based organocobalt(I) [CoCp(CO)(fumarate)] catalysts is synthesized and characterized by X-ray crystallography, multinuclear (13 C and59 Co) solid-state NMR spectroscopy, and59 Co NQR spectroscopy. Given the dearth of59 Co solid-state NMR studies on CoI compounds, the present work constitutes the first systematic characterization of the59 Co electric field gradient and chemical shift tensors for a series of cobalt complexes in this oxidation state. Using X-ray crystallography, the molecular geometry about the CoI centre is found to be nearly identical in all compounds studied herein. Owing to the59 Co nucleus' large chemical shift range, solid-state NMR experiments are found to be able to detect small structural differences between the individual organocobalt(I) compounds. With the aid of density functional theory calculations on these complexes, it is shown that the59 Co chemical shift anisotropy and the59 Co quadrupolar coupling constant are both extremely sensitive gauges of the Fu-Co-Cp bond angle, providing a link between these59 Co NMR observables and the catalysts' structures.