Size-dependent emission characteristics of airborne parent and halogenated PAHs from municipal solid waste incinerators in Shenzhen, China.

Two waste incinerators were selected for investigation of size-dependent emission characteristics of airborne parent and halogenated PAHs (PAHs and HPAHs) and incidence of these pollutants from trash incineration. The concentrations of total PAHs (gas and particles with aerodynamic diameter 0.43-10 μm) in ambient air of Shenzhen incinerators were at the lower end of the global range while those of HPAHs were higher than those of urban air in other studies. High-ring PAHs dominated in PM2.5 (66%-86%), while low-ring PAHs dominated in PM10 (83%-86%). As for PAHs in gaseous phase, low-ring PAHs were collectively account for 86%-97%. ΣHPAH mainly enriched in coarse particles (>83%). The size distributions of ΣPAH and ΣHPAH were both characterized by bimodal peaks dominate in 9.0-10 μm and subordinate in 4.7-5.8 μm. PAHs and HPAHs enrichment in the coarse particles indicates that particle-bound PAHs and HPAHs from incinerators cannot travel great distances. Model simulation results showed the peak of airborne PAHs and HPAHs occurred in approximate 300 m from incinerator, then their concentrations reduced sharply. The extent of affected areas by municipal solid waste incinerators (MSWIs) seem very large, intensity of impacts can be neglected for the very low level of pollutants. Although waste incineration is perceived as most polluting way to manage waste, our study found the damage from incinerator to be far less than originally feared.