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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Amycolamycins A and B, Two Enediyne-Derived Compounds from a Locust-Associated Actinomycete.
Organic Letters 2017 November 18
Two novel enediyne-derived natural products, amycolamycins A and B (1 and 2), were characterized from a locust-associated actinomycete Amycolatopsis sp. HCa4. Amycolamycins A and B contain a unique 2-(cyclopenta[a]inden-5-yl)oxirane core with suspected enediyne polyketide biosynthetic origin. Sequencing and analysis of the acm biosynthetic gene cluster allowed us to propose the biosynthetic pathway of 1 and 2. Moreover, amycolamycin A (1) was selectively cytotoxic to the M231 breast cancer cell line.
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