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Synergistic effects of metal salt and ionic liquid on the pretreatment of sugarcane bagasse for enhanced enzymatic hydrolysis.
Bioresource Technology 2018 Februrary
High cost of ionic liquids (ILs) restricts the industrial application of IL-mediated lignocellulose pretreatment. In this study, a simple and economic technology for the pretreatment of natural lignocellulose was developed. The delignification capacity of aqueous choline ornithine ([Cho][Orn]) and hemicellulose-removal capacity of metal salt FeCl2 were combined. The changes of morphological structure and composition indicated a synergistic interaction of [Cho][Orn] and FeCl2 in the pretreatment process. The delignification and hemicellulose-removal capacity of aqueous [Cho][Orn]50% solution was significantly improved in the presence of FeCl2 by 28% and 53%, respectively. The combination use of FeCl2 and [Cho][Orn] made it possible to save the amount of IL used for pretreatment in half. Enhancement effect of metal salts on the IL-pretreatment efficiency was proved.
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