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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
Diastereoselective Synthesis of Functionalized Diketopiperazines through Post-transformational Reactions.
Journal of Organic Chemistry 2017 December 2
A diversity-oriented access to diastereoselective arylidene 2,5-diketopiperazines is elaborated via a sequential Ugi post-transformation involving catalytic cyclization and oxidative Heck reaction sequence. This sequence offers an interesting multicomponent entry to a library of 2,5-diketopiperazines and arylidene 2,5-diketopiperazines under mild reaction conditions in good to excellent yields.
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