Three-Fold-Symmetric Selenium-Donor Metallaboratranes of Cobalt and Nickel.

A novel selenium-containing pyridazinyl-based soft scorpionate ligand (KTnse) was synthesized. It reacts with CoCl2 and NiCl2 , yielding the first metallaboratrane complexes with selenium in their donor positions. Further substitution with Ag(OTf) or NaN3 allows isolation of the respective triflate or azide complexes. Reaction with Ag(OTf) leads in the case of nickel to a dinuclear, dicationic complex with a short Ni-Ni distance, while cobalt gave a mononuclear cationic species. Substitution of the chloride by azide yields with both metals the respective azide complexes. All compounds were characterized via single-crystal X-ray diffraction analysis. Density functional theory calculations on the chloride species point to oxidized cobalt(III) and nickel(III) centers.