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A microporous MOF with open metal sites and Lewis basic sites for selective CO 2 capture.

Jinjie Qian, Qipeng Li, Linfeng Liang, Ting-Ting Li, Yue Hu, Shaoming Huang
Dalton Transactions : An International Journal of Inorganic Chemistry 2017 October 25
A robust indium-organic framework (InOF-15) with open metal sites and Lewis basic sites has been successfully synthesized using a quinoline-based dicarboxylic acid. Moreover, it exhibits high IAST selective CO2 sorption from CO2 /CH4 and CO2 /N2 mixtures at 273 K, which has been attributed to the coexistence of OMSs and LBSs with strong synergistic effects.

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