Adsorption of tricresyl phosphate onto graphene nanomaterials from aqueous solution.

Phosphorus flame retardant tricresyl phosphate (TCP) adsorption on graphene nanomaterials from aqueous solutions was explored using batch and column modes. Comparative studies were performed regarding the kinetics and equilibrium of TCP adsorption on graphene oxide (GO) and graphene (G) in batch mode. The adsorption kinetics exhibited a rapid TCP uptake, and experimental data were well described by the pseudo-second-order kinetic model. Adsorption isotherm data of TCP on the two adsorbents displayed an improved TCP removal performance with increasing temperature at pH 5, while experimental data were well described by the Langmuir isotherm model with a maximum adsorption capacity of 87.7 mg·g-1 for G, and 30.7 mg·g-1 for GO) at 303 K. The thermodynamic parameters show that the adsorption reaction is a spontaneous and endothermic process. In addition, dynamic adsorption of TCP in a fixed G column confirmed a faster approach to breakthrough at high flow rate, high influent TCP concentration, and low filling height of adsorbent. Breakthrough data were successfully described by the Thomas and Yoon-Nelson models.