We have located links that may give you full text access.
An Efficient Method for the Synthesis of Boratrane Complexes of Late Transition Metals.
Chemistry : a European Journal 2017 December 23
In a quest for efficient precursors for the synthesis of boratrane complexes of late transition metals, we have developed a useful synthetic method using [L'M(μ-Cl)Clx ]2 as precursors (L'=η6 -p-cymene, M=Ru, x=1; L'=COD, M=Rh, x=0 and L'=Cp*, M=Ir or Rh, x=1; COD=1,5-cyclooctadiene, Cp*=η5 -C5 Me5 ). For example, treatment of Na[(H3 B)bbza] or Na[(H2 B)mp2 ] (bbza=bis(benzothiazol-2-yl)amine; mp=2-mercaptopyridyl) with [L'M(μ-Cl)Clx ]2 yielded [(η6 -p-cymene)RuBH{(NCSC6 H4 )(NR)}2 ] (2; R=NCSC6 H4 ), [{N(NCSC6 H4 )2 }RhBH{(NCSC6 H4 )(NR)}2 ] (3; R=NCS-C6 H4 ), [(η6 -p-cymene)RuBH(L)2 ] (5; L=C5 H4 NS), and [Cp*MBH(L)2 ] (6 and 7; L=C5 H4 NS, M=Ir or Rh). In order to delineate the significance of the ligands, we studied the reactivity of [(COD)Rh(μ-Cl)]2 with Na[(H3 B)bbza], which led to the formation of the isomeric agostic complexes [(η4 -COD)Rh(μ-H)BHRh(C14 H8 N3 S2 )3 ], 4 a and 4 b, in parallel to the formation of 16-electron square-pyramidal rhodaboratrane complex 3. Compounds 4 a and 4 b show two different geometries, in which the Rh-B bonds are shorter than in the reported Rh agostic complexes. The new compounds have been characterized in solution by various spectroscopic analyses, and their structural arrangements have been unequivocally established by crystallographic analyses. DFT calculations provide useful insights regarding the stability of these metallaboratrane complexes as well as their M→B bonding interactions.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app