High-intensity focused ultrasound selective annealing induced patterned and gradient crystallization behavior of polymer.

High-intensity focused ultrasound (HIFU) was developed as a spatial selective annealing method to control the crystallization behavior and performance of polymer using amorphous polyethylene terephthalate (PET) as an example for demonstration. The spatial crystallization and morphological details of HIFU induced crystallization areas at the lamellar level and spherulite scale were studied by Micro-Focus hard X-ray diffraction, small angle X-ray scattering and optical microscopy. According to the distribution of crystallinity of PET, we can indirectly detect the history of thermal distribution of the ultrasonic focal point, which is hard to obtain by other methods. The crystallinity and the area of the crystalline region of PET sample increased with ultrasound power or irradiation time. Different from common crystalline structure of polymer materials, HIFU induced crystallinity of PET has a significant gradient distribution. The gradient crystal structure leads to a better mechanical performances, which can realize the good balance between toughness and strength. Ultrasound annealing, as a complement and development of the traditional annealing technology, has the characteristics of high efficient and spatial selectivity, showing great application prospect in post processing field.