Hydrogen-Bonding Interactions in Luminescent Quinoline-Triazoles with Dominant 1D Crystals.

Quinoline-triazoles 2-((4-(diethoxymethyl)-1 H -1,2,3-triazol-1-yl)methyl)quinoline ( 1 ), 2-((4-(m-tolyl)-1 H -1,2,3-triazol-1-yl)methyl)quinoline ( 2 ) and 2-((4-(p-tolyl)-1 H -1,2,3-triazol-1-yl)methyl)quinoline ( 3 ) have been prepared with CuAAC click reactions and used as a model series to probe the relationship between lattice H-bonding interaction and crystal direction of growth. Crystals of 1 - 3 are 1D tape and prism shapes that correlate with their intermolecular and solvent 1D lattice H-bonding interactions. All compounds were thermally stable up to about 200 C and blue-green emissive in solution.