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Copper-mediated phospha-annulation to attain water-soluble polycyclic luminophores.

A 6-membered P-heterocycle has been fused with a polyaromatic framework through intramolecular transformation of anthracene-based phosphine induced by CuCl2 . The resulting water soluble phosphonium fluorophores exhibit extremely high quantum efficiency along with prominent stability and low toxicity that make them suitable for one- and two-photon imaging purposes.

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