We have located links that may give you full text access.
Journal Article
Research Support, Non-U.S. Gov't
Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex.
Angewandte Chemie 2017 November 7
Facile oxygenation of the acyclic amido-chlorosilylene bis(N-heterocyclic carbene) Ni0 complex [{N(Dipp)(SiMe3 )ClSi:→Ni(NHC)2 ] (1; Dipp=2,6-i Pr2 C6 H4 ; N-heterocyclic carbene=C[(i Pr)NC(Me)]2 ) with N2 O furnishes the first Si-metalated iminosilane, [DippN=Si(OSiMe3 )Ni(Cl)(NHC)2 ] (3), in a rearrangement cascade. Markedly, the formation of 3 proceeds via the silanone (Si=O)-Ni π-complex 2 as the initial product, which was predicted by DFT calculations and observed spectroscopically. The Si=O and Si=N moieties in 2 and 3, respectively, show remarkable hydroboration reactivity towards H-B bonds of boranes, in the former case corroborating the proposed formation of a (Si=O)-Ni π-complex at low temperature.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app