We have located links that may give you full text access.
Infrared Signature of Structural Isomers of Gas-Phase M + (N 2 O) n (M = Cu, Ag, Au) Ion-Molecule Complexes.
Journal of Physical Chemistry. A 2017 October 13
Gas-phase metal ion-ligand complexes offer model environments to study molecular interactions that are key to many catalytic processes. Here, we present a combined experimental and computational study of M+ (N2 O)n [M = Cu, Ag, Au; n = 2-7] complexes. The spectra provide clear evidence for both nitrogen- and oxygen-bound ligands giving rise to a wide range of structural isomers for each complex studied. The evolution of the complex structures observed as well as spectral trends for each metal center are interpreted in terms of a molecular orbital binding picture and resulting calculated ligand binding energies. Given the environmental importance of nitrogen oxides, these results have implications for metal-catalyzed removal of nitrous oxide and, particularly, the prospect of initiating infrared-driven isomer-selective chemistry in size-selected complexes.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app